Material safety data sheet

EPA Reg. No.: 51036-322-73273 Effective Date: 07/01/2001 MATERIAL SAFETY DATA SHEET
Product Number

Note: Be sure to compare the EPA registration number as given on the MSDS with the EPA registration number
as given on the label as some products have had the active ingredients changed without a corresponding
change in the UPC number or in the item description.

1. INGREDIENTS:
(3-phenoxyphenyl) methyl-cis, trans-3-(2,2-dichloroethyenyl) - 2,2 dimethylcyclopropanecarboxylate)
2. PHYSICAL
FIRST AID MEASURES:
IF SWALLOWED:
Call a poison control center or doctor immediately for treatment advice. Have person sip a glass of water if able to swallow. Do not induce vomiting unless told to do so by the poison control center or doctor. Do not give anything by mouth to an unconscious person. Take off contaminated clothing. Rinse skin with plenty of water for 15-20 minutes. Call a poison control center or doctor for treatment advice. Hold eye open and rinse slowly and gently with water for 15-20 minutes. Remove contact lenses, if present, after the first five minutes, then continue rinsing eye. Call a poison control center or doctor for treatment advice. Move person to fresh air. If person is not breathing, call 911 or an ambulance, then give artificial respiration, preferably mouth-to-mouth if possible. Call a poison control center or doctor for further treatment advice. FIRE AND EXPLOSION HAZARD DATA:
FLASH POINT (METHOD):
Use foam, dry chemical, carbon dioxide, or water spray when fighting fires involving this material. Can burn in fire. Irritating and toxic gases may be generated by thermal decomposition or combustion. Self-contained breathing apparatus with full facepiece. Full firefighting turn-out gear (Bunker gear). EPA Reg. No.: 51036-322-73273 Effective Date: 07/01/2001 Evacuate area and fight fire upwind from a safe distance to avoid hazardous vapors and decomposition products. Dike and collect water used to fight fire to prevent environmental damage due to run off. foam or dry chemical fire extinguishing systems are preferred to prevent environmental damage from excessive water run off. Carbon monoxide and/or carbon dioxide. chlorine and hydrogen chloride may be formed. STABILITY & REACTIVITY DATA:
STABILITY:
Stable, however may decompose if heated. Thermal decomposition may release carbon dioxide, carbon monoxide, sulfur oxides, halogen, halogen acids and possible trace amounts of carbonyl halide.
6. ECOLOGICAL
INFORMATION:
This product is extremely toxic to fish and aquatic invertebrates. It is moderately toxic to birds, and other wildlife. Do not apply directly to water, or to areas where surface water is present. Do not apply where runoff is likely to occur. Do not contaminate water when disposing of equipment washwaters. Oral LD50, Japanese quail - > 13,500 mg/Kg DISPOSAL CONSIDERATIONS:
WASTE:
Dispose of in accordance with applicable Federal, state and local laws and regulations. Clean up spills immediately, observing precautions in Section 8 of this document. SMALL SPILL: Vacuum or sweep up material and place in a container for reuse or disposal. LARGE SPILL: Same as for small spill. After removal flush and neutralize contaminated area thoroughly with water and a diluted solution of soda ash or bleach. Pick up wash liquid with absorbent and place in chemical waste container for disposal. This material is a water pollutant and should be prevented from entering sewage and drainage systems and bodies of water. HANDLING AND STORAGE:
HANDLING:
Store product in its original labeled container in a cool, dry locked place out of reach of children. HEALTH HAZARD DATA:
EMERGENCY OVERVIEW:
Light brown granules. Avoid breathing dust. Avoid contact with eyes. Keep out of reach of children. EPA Reg. No.: 51036-322-73273 Effective Date: 07/01/2001 May cause skin irritation, numbing, burning and tingling. Extremely toxic to fish, other water organisms and bees. Keep out of waterways. EXPOSURE CONTROLS, PERSONAL PROTECTION:
EXPOSURE LIMITS (8-HR TWA): (Refer to Section 7)
ENGINEERING CONTROLS:
Ventilation is normally required when handling or using this product to keep exposure to airborne contaminants below the exposure limit. Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Long-sleeved shirt and long pants. Shoes plus socks. When handling in enclosed areas where exposure limits may be exceeded, use a dust/mist filtering respirator (MSHA/NIOSH approval number prefix TC-21C). Follow manufacturer's instructions for cleaning and maintaining PPE. If no such instructions for washables, use detergent and hot water. Keep and wash PPE separately from other laundry. USER SAFETY RECOMMENDATIONS: Wash hands before eating, drinking, chewing gum, using tobacco or using the toilet. Remove clothing immediately if pesticides gets inside. Then wash thoroughly and put on clean clothing.
9. TOXICOLOGICAL
INFORMATION:
ACUTE TOXICITY:
ORAL LD50 (rat):
MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE: CARCINOGEN STATUS:
MUTAGENIC DATA:
Not evidence of effects during in vivo or in vitro studies. ADDITIONAL DATA:
Not known to exhibit reproductive or birth defects. Repeated or prolonged low level exposure may cause sensitization to subsequent exposures.
10. TRANSPORT
INFORMATION:
Agricultural Insecticide, Solid, N.O.I.B.N. DOT PRIMARY/SECONDARY LABEL: None required. EPA Reg. No.: 51036-322-73273 Effective Date: 07/01/2001
11. REGULATORY
INFORMATION:
All pesticides are governed under the Federal Insecticide, Fungicide, and Rodenticide Act. The regulatory information presented below is pertinent only when this product is handled outside of the normal use and application as a pesticide. OSHA HAZARD COMMUNICATION STANDARD STATUS: CERCLA REPORTABLE QUANTITY: N/A
SARA TITLE III STATUS:
302 Extremely Hazardous Substance: No 311/312 Hazard Categories: The information presented herein is based on available data from reliable sources and is correct to the best of our knowledge. Green Light makes no warranty, express or implied, regarding the accuracy of the data or the results obtained from the use of this product. Nothing herein may be construed as recommending any practice or any product in violation of any law or regulations. The user is solely responsible for determining the suitability of any material or product for a specific purpose and for adopting any appropriate safety precautions. We disclaim all liability for injury or damage stemming from any improper use of the material or product described herein.

Source: http://www.lamarpa.edu/dept/pp/msds/Grounds%20Keeping/SWCP_Permethrin_Granules_msds.pdf