Safety data sheet according to 1907/2006/EC, Article 31 / ISO 11014 Printing date 26.07.2011 Version number 1 Revision: 26.07.2011 1Identification of the substance/mixture and of the company/undertaking
· Product identifier
· Trade name: Hilti HIT-HY 200-A · Container size 330 ml, 500 ml · Relevant identified uses of the substance or mixture and uses advised against · Sector of Use Building and construction work · Product category Adhesives, sealants · Application of the substance / the preparation Adhesive mortar for anchor and rebar fastenings
· Details of the supplier of the safety data sheet · Manufacturer/Supplier:
Hilti AGFeldkircherstr. 100Postfach 333FL-9494 SchaanLiechtensteinTel: 00423 / 234 2111Fax: 00423 / 234 2965
· Informing department:
· Emergency telephone number:
Hilti AGTel: 00423 / 234 2111Fax: 00423 / 234 2965Schweizerisches Toxikologisches Informationszentrum - 24 h ServiceTel.: 0041 / 1 251 51 51 (international)
2Hazards identification
· Classification of the substance or mixture · Classification according to Regulation (EC) No 1272/2008
Skin Irrit. 2 H315 Causes skin irritation.
Skin Sens. 1 H317 May cause an allergic skin reaction.
· Classification according to Directive 67/548/EEC or Directive 1999/45/EC · Information concerning particular hazards for human and environment:
The product has to be labelled due to the calculation procedure of the "General Classification guideline for preparations of the EU" in thelatest valid version.
· Classification system:
The classification is in line with current EC lists. It is expanded, however, by information from technical literature and by informationfurnished by supplier companies.
· Label elements · Labelling according to Regulation (EC) No 1272/2008 The product is classified and labelled according to the CLP regulation. · Hazard pictograms
· Signal word Warning
· Hazard-determining components of labelling:
methacrylic acid, monoester with propane-1,2-dioldibenzoyl peroxide
· Hazard statements
H315 Causes skin irritation. H319 Causes serious eye irritation. H317 May cause an allergic skin reaction.
· Precautionary statements
Do not get in eyes, on skin, or on clothing.
Wear protective gloves/protective clothing/eye protection/face protection.
IF ON SKIN: Wash with plenty of soap and water.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do.
If skin irritation or rash occurs: Get medical advice/attention.
If eye irritation persists: Get medical advice/attention.
Store at temperatures not exceeding 25°C. Keep cool. Safety data sheet according to 1907/2006/EC, Article 31 / ISO 11014 Printing date 26.07.2011 Version number 1 Revision: 26.07.2011 Trade name: Hilti HIT-HY 200-A
· Other hazards · Results of PBT and vPvB assessment · PBT: Not applicable. · vPvB: Not applicable.
· Additional information:
· Information pertaining to particular dangers for man and environment: A
H315 Causes skin irritation. H319 Causes serious eye irritation. H317 May cause an allergic skin reaction.
· Information pertaining to particular dangers for man and environment: B
H319 Causes serious eye irritation. H317 May cause an allergic skin reaction. 3Composition/information on ingredients
· Chemical characterization: Mixtures · Description:
2-Component-foilpack, contains:Component A: Urethane methacrylate resin, inorganic fillerComponent B: Dibenzoyl peroxide, phlegmatized
Mixture of the substances listed below with harmless additions.
· Dangerous components:
Xi R36/38 Skin Irrit. 2, H315; Eye Irrit. 2, H319
methacrylic acid, monoester with propane-1,2-diol
· Dangerous components A:
Xi R36/38 Skin Irrit. 2, H315; Eye Irrit. 2, H319
methacrylic acid, monoester with propane-1,2-diol
· Dangerous components B:
· SVHC None · Additional information For the wording of the listed risk phrases refer to section 16. 4First aid measures
· Description of first aid measures · General information Instantly remove any clothing soiled by the product. · After inhalation Take affected persons into the open air and position comfortably · After skin contact Instantly wash with water and soap and rinse thoroughly. If skin irritation persist, call a physician. · After eye contact
Rinse thoroughly with plenty of water for at least 15 minutes and consult a physician. Protect unharmed eye.
· After swallowing
Rinse out mouth and then drink plenty of water. Seek immediate medical advice.
· Information for doctor · Most important symptoms and effects, both acute and delayed Allergic reactions · Indication of any immediate medical attention and special treatment needed No further relevant information available. Safety data sheet according to 1907/2006/EC, Article 31 / ISO 11014 Printing date 26.07.2011 Version number 1 Revision: 26.07.2011 Trade name: Hilti HIT-HY 200-A 5Firefighting measures
· Extinguishing media · Suitable extinguishing agents Water spray, carbon dioxide (CO2), carbon dioxide blanket, foam, or dry powder. · For safety reasons unsuitable extinguishing agents Water with full jet. · Special hazards arising from the substance or mixture
Can be released in case of fireNitrogen oxides (NOx)Carbon monoxide (CO)Carbon dioxide (CO2)Under certain fire conditions, traces of other toxic gases cannot be excluded.
· Advice for firefighters · Protective equipment: In the event of fire, wear self contained breathing apparatus 6Accidental release measures
· Personal precautions, protective equipment and emergency procedures
Wear protective equipment. Keep unprotected persons away. Use personal protective equipment. Ensure adequate ventilation. Remove all sources of ignition.
· Environmental precautions: Do not allow to enter the ground/soil. · Methods and material for containment and cleaning up:
Collect mechanically. Clean the accident area carefully; suitable cleaners are:organic solventEnsure adequate ventilation. Dispose of contaminated material as waste according to item 13.
· Reference to other sections
See Section 7 for information on safe handlingSee Section 8 for information on personal protection equipment. See Section 13 for information on disposal. 7Handling and storage
· Handling · Precautions for safe handling
Check the expiry date: see imprint on manifold (month/year). Do not use expired mortar!The usual precautionary measures should be adhered to general rules for handling chemicals.
· Information about protection against explosions and fires:
Keep ignition sources away - Do not smoke. Protect from heat.
· Conditions for safe storage, including any incompatibilities · Storage · Requirements to be met by storerooms and containers: Keep in a cool, dry and dark place; 5 °C to 25 °C. · Information about storage in one common storage facility: Store away from foodstuffs. · Further information about storage conditions: Protect from heat and direct sunlight.
· Storage class
As per VCI (1991) storage classification concept. 11
· Specific end use(s) Adhesive mortar for anchor and rebar fastenings 8Exposure controls/personal protection
· Additional information about design of technical systems: No further data; see item 7.
· Control parameters · Components with limit values that require monitoring at the workplace:
The product does not contain any relevant quantities of materials with critical values that have to be monitored at the workplace.
· Additional information: The lists that were valid during the compilation were used as basis.
· Exposure controls · Personal protective equipment · General protective and hygienic measures
The usual precautionary measures should be adhered to general rules for handling chemicals. Keep away from foodstuffs, beverages and food. Wash hands during breaks and at the end of the work. Avoid contact with the eyes and skin. Do not eat, drink or smoke while working.
· Breathing equipment: Not required. · Protection of hands: Safety data sheet according to 1907/2006/EC, Article 31 / ISO 11014 Printing date 26.07.2011 Version number 1 Revision: 26.07.2011 Trade name: Hilti HIT-HY 200-A
Avoid direct contact with the chemical/ the product/ the preparation by organizational measures. If only a short-term loading of the glove material by splashes is expected, tricoted gloves with higher wearability for the better acceptanceof the users are recommended.
· Material of gloves Nitrile rubber, NBR · Penetration time of glove material
The exact break trough time has to be found out by the manufacturer of the protective gloves and has to be observed.
· Not suitable are gloves made of the following materials:
Natural rubber, NRLeather glovesStrong gloves
· Eye protection: Tightly sealed safety glasses. · Body protection: Protective work clothing. 9Physical and chemical properties
· Information on basic physical and chemical properties · General Information · Appearance:
· Odour:
· Odour threshold:
· pH-value:
Component A: not applicableComponent B: ~ 7
· Change in condition Melting point/Melting range: Boiling point/Boiling range:
· Flash point:
Component A: > 109 °C (DIN 53213)Component B: not applicable
· Ignition temperature:
· Decomposition temperature:
Component A: not relevantComponent B: SADT 65°C UN test H4
· Self-inflammability:
· Danger of explosion:
· Critical values for explosion:
· Vapour pressure at 20°C:
· Density at 20°C
· Relative density
· Vapour density
· Evaporation rate
· Solubility in / Miscibility with
· Segregation coefficient (n-octanol/water): Not determined
· Viscosity: dynamic at 20°C: kinematic at 20°C:
· Solvent content:
· Other information
No further relevant information available. 10 Stability and reactivity
· Reactivity · Chemical stability · Thermal decomposition / conditions to be avoided:
To avoid thermal decomposition do not overheat. No decomposition if used and stored according to specifications.
· Possibility of hazardous reactions No dangerous reactions known · Conditions to avoid No further relevant information available. · Incompatible materials: No further relevant information available. Safety data sheet according to 1907/2006/EC, Article 31 / ISO 11014 Printing date 26.07.2011 Version number 1 Revision: 26.07.2011 Trade name: Hilti HIT-HY 200-A
· Hazardous decomposition products: No dangerous decomposition products known 11 Toxicological information
· Information on toxicological effects · Acute toxicity: · Primary irritant effect: · on the skin: Irritant to skin and mucous membranes. · on the eye: Irritant effect. · Sensitization: Sensitization possible by skin contact. · Additional toxicological information:
The product shows the following dangers according to the calculation method of the General EC Classification Guidelines for Preparationsas issued in the latest version:Irritant
12 Ecological information
· Toxicity · Acquatic toxicity: No further relevant information available. · Persistence and degradability No further relevant information available. · Behaviour in environmental systems: · Bioaccumulative potential No further relevant information available. · Mobility in soil No further relevant information available. · Additional ecological information: · According to recipe contains the following heavy metals and compounds according to EC guideline NO. 76/464 EC: None · General notes: The product does not contain organically bounded halogens (AOX-free). · Results of PBT and vPvB assessment · PBT: Not applicable. · vPvB: Not applicable. · Other adverse effects No further relevant information available. 13 Disposal considerations
· Waste treatment methods · Recommendation
After curing, the product can be disposed of with household waste. Full or only partially emptied cartridges must be disposed of as special waste in accordance with official regulations.
· European waste catalogue
08 00 00 WASTES FROM THE MANUFACTURE, FORMULATION, SUPPLY AND USE (MFSU) OF COATINGS (PAINTS,
VARNISHES AND VITREOUS ENAMELS), ADHESIVES, SEALANTS AND PRINTING INKS
08 04 00 wastes from MFSU of adhesives and sealants (including waterproofing products)
08 04 09* waste adhesives and sealants containing organic solvents or other dangerous substances
20 00 00 MUNICIPAL WASTES (HOUSEHOLD WASTE AND SIMILAR COMMERCIAL, INDUSTRIAL AND INSTITUTIONAL
WASTES) INCLUDING SEPARATELY COLLECTED FRACTIONS
20 01 00 separately collected fractions (except 15 01)
20 01 27* paint, inks, adhesives and resins containing dangerous substances
· Uncleaned packagings: · Recommendation:
Empty packs: May be disposed via the local Green Dot collecting system or EAK waste material code 150102 (plastic packaging materials)
14 Transport information
· UN-Number · ADR, ADN, IMDG, IATA
· UN proper shipping name · ADR, ADN, IMDG, IATA
· Transport hazard class(es)
· ADR, ADN, IMDG, IATA · Class
· Packing group · ADR, IMDG, IATA
· Environmental hazards: · Marine pollutant: Safety data sheet according to 1907/2006/EC, Article 31 / ISO 11014 Printing date 26.07.2011 Version number 1 Revision: 26.07.2011 Trade name: Hilti HIT-HY 200-A
· Special precautions for user
· Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code
· Transport/Additional information:
Not dangerous according to the above specifications.
· UN "Model Regulation":
· HS-Code:
3214 10 10: Glaziers' putty, grafting putty, resin cements, caulkingcompounds and other mastics
15 Regulatory information
· Safety, health and environmental regulations/legislation specific for the substance or mixture · Labelling according to Regulation (EC) No 1272/2008 The product is classified and labelled according to the CLP regulation. · Hazard pictograms
· Signal word Warning
· Hazard-determining components of labelling:
methacrylic acid, monoester with propane-1,2-dioldibenzoyl peroxide
· Hazard statements
H315 Causes skin irritation. H319 Causes serious eye irritation. H317 May cause an allergic skin reaction.
· Precautionary statements
Do not get in eyes, on skin, or on clothing.
Wear protective gloves/protective clothing/eye protection/face protection.
IF ON SKIN: Wash with plenty of soap and water.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do.
If skin irritation or rash occurs: Get medical advice/attention.
If eye irritation persists: Get medical advice/attention.
Store at temperatures not exceeding 25°C. Keep cool.
· National regulations
The product is subject to classification in accordance with the prevailing version of the regulations on hazardous materials. Council Directive 89/391/EEC of 12 June 1989 on the introduction of measures to encourage improvements in the safety and health ofworkers at work. Article 12 Training of workers
· Information about limitation of use: Employment restrictions concerning young persons must be observed. · Chemical safety assessment: not required. 16 Other information
These data are based on our present knowledge. However, they shall not constitute a guarantee for any specific product features and shallnot establish a legally valid contractual relationship.
· Relevant phrases
Heating may cause a fire or explosion.
May cause an allergic skin reaction.
Extreme risk of explosion by shock, friction, fire or other sources of ignition.
R36/38 Irritating to eyes and skin. R43
May cause sensitisation by skin contact.
· Department issuing data specification sheet:
Hilti Entwicklungsgesellschaft mbHHiltistrasse 6D-86916 KauferingTel.: +49 8191 906310Fax: +49 8191 906826e-mail: monika.moench@hilti.com
· Contact: Monika Mönch Safety data sheet according to 1907/2006/EC, Article 31 / ISO 11014 Printing date 26.07.2011 Version number 1 Revision: 26.07.2011 Trade name: Hilti HIT-HY 200-A
· Abbreviations and acronyms:
ADR: Accord européen sur le transport des marchandises dangereuses par Route (European Agreement concerning the International Carriage of Dangerous Goods by Road)RID: Règlement international concernant le transport des marchandises dangereuses par chemin de fer (Regulations Concerning the International Transport of Dangerous Goods by Rail)IMDG: International Maritime Code for Dangerous GoodsIATA: International Air Transport AssociationICAO: International Civil Aviation OrganizationGHS: Globally Harmonized System of Classification and Labelling of Chemicals
Country File EL SALVADOR Last updated: December 2008 Legal system UNCAT Ratification/ Accession (a)/ Succession (d) Relevant Laws • Criminal Procedure Code of 4 December 1996 Relevant Articles • Prohibition of Torture: Articles 243 and 262 of the • Definition of Torture: • Penalties: Article 297 of the Penal Code • Others: 1. Defences:
Liability of the Generic Manufacturers American Association for Justice AAJ Topamax Teleseminar April 6, 2011 2:00 pm – 3:30 pm EDT William B. Curtis Javier Gonzalez Curtis Law Group 3100 Monticello Avenue, Suite 500 Dallas, Texas 75205 214.890.1000 214.890.1010 (fax) Introduction Late last year the Supreme Court of the United States granted c