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SAFETY DATA SHEET
Based on Regulation (EC) no. 1907/2006 (REACH) Article 31 and Annex II
Soudafix P380 - ST, B component
Identification of the substance/preparation and of the company/undertaking

1.1 Identification of the substance or preparation:

Productname :

1.2 Use of the substance/preparation:


1.3 Company/undertaking

identification:

1.4 Emergency

telephone:
Brandweerinformatiecentrum voor Gevaarlijke Stoffen (BIG) Technische Schoolstraat 43 A, B-2440 Geel, Belgium
2. Hazards
identification
- May cause sensitization by skin contact Composition/information on ingredients
Hazardous ingredients
Conc.(%)
Hazard
symbol

EINECS/ELINCS No.
(R-phrases)
(1) For R-phrases in full: see heading 16 (2) Substance with a Community workplace exposure limit : Brandweerinformatiecentrum voor Gevaarlijke Stoffen vzw (BIG) Technische Schoolstraat 43 A, B-2440 Geel Soudafix P380 - ST, B component
measures

4.1 After

inhalation:
- Respiratory difficulties: consult a doctor/medical service contact:
- Rinse immediately with plenty of water - Take victim to a doctor if irritation persists contact:
- Take victim to an ophthalmologist if irritation persists
4.4 After

ingestion:
- If you feel unwell: consult a doctor/medical service

5. Fire-fighting
measures

5.1 Suitable extinguishing media:
-

5.2 Unsuitable extinguishing media:
-
- Solid water jet ineffective as extinguishing medium
5.3 Special
exposure
hazards:

5.4 Instructions:

- Cool closed containers with water if they are exposed to the fire - Extinguish/cool from behind cover/unmanned monitors - Do not move the load if exposed to heat
5.5 Special protective equipment for firefighters:

- Heat/fire exposure: compressed air/oxygen apparatus Accidental release measures

6.1 Personal

precautions:

6.2 Environmental
precautions:
- Use appropriate container to avoid environmental contamination
6.3 Methods for cleaning up:

- Start with disposal only in the presence of experts - Spill must not return in its original container - Clean contaminated surfaces with an excess of water - Take collected spill to manufacturer/competent authority - Wash clothing and equipment after handling Soudafix P380 - ST, B component
Handling and storage

7.1 Handling:

- Observe very strict hygiene - avoid contact - Do not discharge the waste into the drain - Handle and open the container with care - Remove contaminated clothing immediately
7.2 Storage:

- Keep away from: heat sources, ignition sources, oxidizing agents, reducing agents, acids, bases, alcohols, amines, combustible materials temperature
Quantity
Materials for packaging

7.3 Specific

- See information supplied by the manufacturer for the identified use(s)
8. Exposure

controls/Personal protection

8.1 Exposure limit values:
8.1.1 Occupational

exposure:

DIBENZOYL PEROXIDE:
TLV-TWA

TLV-STEL
TLV-Ceiling
WEL-LTEL : 5
WEL-STEL : -
5 E mg/m³
GWBNL-TGG 8 h
mg/m3 (indicatief)
GWKNL-TGG 15 min.
Momentary
Soudafix P380 - ST, B component

GLYCEROL:
TLV-TWA

TLV-STEL
TLV-Ceiling
WEL-LTEL : 10 mist
WEL-STEL : -
GWBNL-TGG 8 h
: 10 nevel
mg/m3 (indicatief)
GWKNL-TGG 15 min.
: 10 aéros.
: 10 nevel
Momentary

8.1.2 Sampling

methods:
- Benzoyl Peroxide NIOSH 5009 - Benzoyl Peroxide OSHA CSI - Glycerin Mist (Particulates) NIOSH 600 - Glycerin Mist (Respirable Fraction) OSHA CSI - Glycerin Mist (Total Dust) OSHA CSI
8.2 Exposure

controls:
Occupational exposure controls:
Measure the concentration in the air regularly
Personal

protective
equipment:
Respiratory
protection:
Gas mask with filter type A at conc. in air > exposure limit protection:
Material
Breakthrough time (min)
Thickness (mm)
protection:
protection:
Environmental exposure controls: see heading 6.2, 6.3 and 13
Soudafix P380 - ST, B component
Physical and chemical properties

9.1 General

information:

9.2 Important health, safety and environmental information:

Explosion limits (explosive properties) : N.D.
9.3 Other

information:

10. Stability

reactivity

10.1 Conditions to avoid:


10.2 Materials to avoid:

- Keep away from: heat sources, ignition sources, oxidizing agents, reducing agents, acids, bases, alcohols, amines, combustible materials
10.3 Hazardous decomposition products:

- Violent to explosive reaction with many compounds e.g.: with (strong) reducers, with (some) acids/bases, with combustible materials, with alcohols and with amines Soudafix P380 - ST, B component

11. Toxicological

information

11.1 Acute toxicity:
DIBENZOYL PEROXIDE:

LD50 oral rat

GLYCEROL:

LD50 oral rat
LD50 dermal rabbit
: > 10000 mg/kg


11.2 Chronic toxicity:

DIBENZOYL PEROXIDE:


Carcinogenicity (TLV)
IARC classification


GLYCEROL:


Teratogenicity (MAK)

11.3 Routes of exposure:


11.4 Acute effects/symptoms:

AFTER EYE CONTACT:

11.5 Chronic effects:

- May cause sensitization by skin contact - Not listed in carcinogenicity class (IARC,EC,TLV,MAK) - Not listed in mutagenicity class (EC,MAK) - Not classified as toxic to reproduction (EC) Soudafix P380 - ST, B component

12. Ecological

information

12.1 Ecotoxicity:
DIBENZOYL PEROXIDE:

- LC50 (96 h) : 2 mg/l (POECILIA RETICULATA)
GLYCEROL:

- LC50 (96 h) : 54000 mg/l (SALMO GAIRDNERI/ ONCORHYNCHUS MYKISS) - EC50 (24 h) : >10000 mg/l (DAPHNIA MAGNA) - Effect on waste water purification


12.2 Mobility:
-
Volatile organic compounds (VOC): 0%
For other physicochemical properties see heading 9
12.3 Persistence and degradability:

- Biodegradation BOD5 :

12.4 Bioaccumulative potential:


12.5 Results of PBT assessment:
- Not applicable, on the basis of the available data.
12.6 Other adverse effects:

(Classification based on the components in compliance with Verwaltungsvorschrift wassergefährdender Stoffe (VwVwS) of 27 July 2005 (Anhang 4)) - Effect on the ozone layer
- Greenhouse effect

13. Disposal
considerations


13.1 Provisions relating to waste:

- Waste material code (91/689/EEC, Council Decision 2001/118/EC, O.J. L47 of 16/2/2001): 16 05 08* (discarded organic chemicals consisting of or containing dangerous substances) 16 09 03* (peroxides, for example hydrogen peroxide) - LWCA (the Netherlands): KGA category 06 - Remove waste in accordance with local and/or national regulations
13.2 Disposal methods:

- Incinerate under surveillance with energy recovery - Do not discharge into drains or the environment
13.3 Packaging:
- Waste material code packaging (91/689/EEC, Council Decision 2001/118/EC, O.J. L47 of 16/2/2001): 15 01 10* (packaging containing residues of or contaminated by dangerous substances) Soudafix P380 - ST, B component


14. Transport

information

14.1 Classification of the substance in compliance with UN Recommendations
UN

14.2 ADR (transport by road)
CLASSIFICATION
PACKAGES
TUNNEL RESTRICTION CODE
PROPER SHIPPING NAME
Organic peroxide type E, solid (dibenzoyl peroxide) 14.3 RID (transport by rail)
CLASSIFICATION
PACKAGES
PROPER SHIPPING NAME
Organic peroxide type E, solid (dibenzoyl peroxide) 14.4 ADNR (transport by inland waterways)
CLASSIFICATION
PACKAGES
14.5 IMDG (maritime transport)
POLLUTANT
14.6 ICAO (air freight)
PACKING INSTRUCTIONS PASSENGER AIRCRAFT
PACKING INSTRUCTIONS CARGO AIRCRAFT
14.7 Special precautions
: Rail and road transport: not
14.8 Limited quantities (LQ)
When substances and their packaging meet the conditions established by ADR/RID/ADNR in chapter 3.4, only the following prescriptions shall be complied with: each package shall display a diamond-shaped figure with the following inscription: - 'UN 3108' or, in the case of different goods with different identification numbers within a single package: - the letters 'LQ' Soudafix P380 - ST, B component

15. Regulatory
information


15.1 EU Legislation:

Labelling in accordance with EC directives 67/548/EEC, 1999/45/EC and
2006/8/EC

Keep container tightly closed in a cool place Keep away from reducing agents/(strong) acids/ (strong) bases and metals Wear suitable protective clothing gloves, and eye/face protection (If swallowed, seek medical advice immediately and show this container or label)
15.2 National provisions:
the Netherlands:
Germany:
WGK
(Classification based on the components in compliance with Verwaltungsvorschrift wassergefährdender Stoffe (VwVwS) of 27 July 2005 (Anhang 4)) Soudafix P380 - ST, B component

16. Other
information
The information provided on this SDS is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered as a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other material or in any process, unless specified in the text.
PBT-substances = persistent, bioaccumulative and toxic substances
Exposure limits:
TLV

Workplace Exposure Limits - United Kingdom Technische Regel für Gefahrstoffe 900 (Arbeitsplatzgrenzwerte) - Germany Maximale Arbeitsplatzkonzentrationen - Germany Grenswaarde voor blootstelling - the Netherlands Grenswaarde korte duur - the Netherlands Valeurs limites de Moyenne d’Exposition - France Valeurs limites d’Exposition à court terme - France Grenswaarde beroepsmatige blootstelling - Belgium Grenswaarde kortstondige blootstelling - Belgium Indicative occupational exposure limit values I : Inhalable fraction = T : Total dust = E : Einatembarer Aerosolanteil
R : Respirable fraction = A : Alveolengängiger Aerosolanteil/Alveolar dust
C : Ceiling limit

Chronic toxicity:
K

List of the carcinogenic substances and processes - The Netherlands
Full text of any R-phrases referred to under headings 2 and 3:
Risk of explosion by shock, friction, fire or other sources of ignition Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment May cause long-term adverse effects in the aquatic environment

Source: http://www.3kltd.com.tr/upload/pdf/soudal/soudafix-p380-st-b-component.pdf

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