Epirez Ezirender HB Primer Chemwatch Material Safety Data Sheet Issue Date: 21-Jan-2011 CHEMWATCH 5139-85 Version No:3 CD 2011/1 Page 1 of 6 Section 1 - CHEMICAL PRODUCT AND COMPANY IDENTIFICATION PRODUCT NAME Epirez Ezirender HB Primer PRODUCT USE ■ Used according to manufacturer's directions. Single pack water based primer. Single pack water based primer. SUPPLIER Company: ITW POLYMERS & FLUIDS Address: 100 Hassall Street Wetherill Park NSW, 2164 Australia Telephone: +61 2 9757 8800 Emergency Tel: 1800 039 008 Emergency Tel: +61 3 9573 3112 Fax: +61 2 9757 3855 Section 2 - HAZARDS IDENTIFICATION STATEMENT OF HAZARDOUS NATURE HAZARDOUS SUBSTANCE. NON-DANGEROUS GOODS. According to NOHSC Criteria, and ADG Code.
• Do not breathe gas/fumes/vapour/spray.
• Use only in well ventilated areas.
• Keep container in a well ventilated place. • Avoid exposure - obtain special instructions before use. • To clean the floor and all objects contaminated by thismaterial, use water. • Keep container tightly closed. • Keep away from food, drink and animal feeding stuffs. • If swallowed, IMMEDIATELY contact Doctor or PoisonsInformation Centre. (show this container or label). Section 3 - COMPOSITION / INFORMATION ON INGREDIENTS
other ingredients not contributing to the classification
continued. Epirez Ezirender HB Primer Chemwatch Material Safety Data Sheet Issue Date: 21-Jan-2011 CHEMWATCH 5139-85 Version No:3 CD 2011/1 Page 2 of 6 Section 4 - FIRST AID MEASURES SWALLOWED • If spontaneous vomiting appears imminent or occurs, hold patient's head down, lower than their hips to help avoid possible aspiration of vomitus. • If swallowed do NOT induce vomiting. • If vomiting occurs, lean patient forward or place on left side (head-down position, if possible) to maintain open airway and prevent aspiration. • Observe the patient carefully. • Never give liquid to a person showing signs of being sleepy or with reduced awareness; i.e. becoming unconscious. EYE ■ If this product comes in contact with the eyes: • Wash out immediately with fresh running water. • Ensure complete irrigation of the eye by keeping eyelids apart and away from eye and moving the eyelids by occasionally lifting the upper and lower lids. • Seek medical attention without delay; if pain persists or recurs seek medical attention. • Removal of contact lenses after an eye injury should only be undertaken by skilled personnel. SKIN ■ If skin contact occurs: • Immediately remove all contaminated clothing, including footwear. • Flush skin and hair with running water (and soap if available). • Seek medical attention in event of irritation. INHALED • If fumes or combustion products are inhaled remove from contaminated area. • Lay patient down. Keep warm and rested. • Prostheses such as false teeth, which may block airway, should be removed, where possible, prior to initiating first aid procedures. • Apply artificial respiration if not breathing, preferably with a demand valve resuscitator, bag-valve mask device, or pocket mask as trained. Perform CPR if necessary. NOTES TO PHYSICIAN ■ For acute or short term repeated exposures to ethylene glycol: • Early treatment of ingestion is important. Ensure emesis is satisfactory. • Test and correct for metabolic acidosis and hypocalcaemia. • Apply sustained diuresis when possible with hypertonic mannitol. • Evaluate renal status and begin haemodialysis if indicated. [I.L.O]. To treat poisoning by the higher aliphatic alcohols (up to C7): •
Gastric lavage with copious amounts of water.
• It may be beneficial to instill 60 ml of mineral oil into the stomach. • Oxygen and artificial respiration as needed. • Electrolyte balance: it may be useful to start 500 ml. M/6 sodium bicarbonate intravenously but maintain a cautious and
conservative attitude toward electrolyte replacement unless shock or severe acidosis threatens.
Any material aspirated during vomiting may produce lung injury. Therefore emesis should not be induced mechanically orpharmacologically. Section 5 - FIRE FIGHTING MEASURES EXTINGUISHING MEDIA • Alcohol stable foam. • Dry chemical powder. • BCF (where regulations permit). • Carbon dioxide. FIRE FIGHTING • Alert Fire Brigade and tell them location and nature of hazard. • Wear breathing apparatus plus protective gloves for fire only. • Prevent, by any means available, spillage from entering drains or water courses. • Use fire fighting procedures suitable for surrounding area. FIRE/EXPLOSION HAZARD • Non combustible. • Not considered a significant fire risk, however containers may burn. May emit poisonous fumes. continued. Epirez Ezirender HB Primer Chemwatch Material Safety Data Sheet Issue Date: 21-Jan-2011 CHEMWATCH 5139-85 Version No:3 CD 2011/1 Page 3 of 6 Section 5 - FIRE FIGHTING MEASURES FIRE INCOMPATIBILITY ■ None known. HAZCHEM None Personal Protective Equipment Gloves, boots (chemical resistant). Breathing apparatus. Section 6 - ACCIDENTAL RELEASE MEASURES MINOR SPILLS • Clean up all spills immediately. • Avoid breathing vapours and contact with skin and eyes. • Control personal contact by using protective equipment. • Contain and absorb spill with sand, earth, inert material or vermiculite. MAJOR SPILLS ■ Moderate hazard. • Clear area of personnel and move upwind. • Alert Fire Brigade and tell them location and nature of hazard. • Wear breathing apparatus plus protective gloves. • Prevent, by any means available, spillage from entering drains or water course. Personal Protective Equipment advice is contained in Section 8 of the MSDS. Section 7 - HANDLING AND STORAGE PROCEDURE FOR HANDLING • Avoid all personal contact, including inhalation. • Wear protective clothing when risk of exposure occurs. • Use in a well-ventilated area. • Avoid contact with moisture. • DO NOT allow clothing wet with material to stay in contact with skin. SUITABLE CONTAINER • Polyethylene or polypropylene container. • Packing as recommended by manufacturer. • Check all containers are clearly labelled and free from leaks. STORAGE INCOMPATIBILITY ■ *. Alcohols • are incompatible with strong acids, acid chlorides, acid anhydrides, oxidising and reducing agents. • reacts, possibly violently, with alkaline metals and alkaline earth metals to produce hydrogen • react with strong acids, strong caustics, aliphatic amines, isocyanates, acetaldehyde, benzoyl peroxide, chromic acid, chromium oxide, dialkylzincs, dichlorine oxide, ethylene oxide, hypochlorous acid, isopropyl chlorocarbonate, lithium tetrahydroaluminate, nitrogen dioxide, pentafluoroguanidine, phosphorus halides, phosphorus pentasulfide, tangerine oil, triethylaluminium, triisobutylaluminium • should not be heated above 49 deg. C. when in contact with aluminium equipment. None known. STORAGE REQUIREMENTS • Store in original containers. • Keep containers securely sealed. • Store in a cool, dry, well-ventilated area. • Store away from incompatible materials and foodstuff containers. continued. Epirez Ezirender HB Primer Chemwatch Material Safety Data Sheet Issue Date: 21-Jan-2011 CHEMWATCH 5139-85 Version No:3 CD 2011/1 Page 4 of 6 Section 8 - EXPOSURE CONTROLS / PERSONAL PROTECTION EXPOSURE CONTROLS Source PERSONAL PROTECTION RESPIRATOR Type AK-P Filter of sufficient capacity EYE • Safety glasses with side shields. • Chemical goggles. • Contact lenses may pose a special hazard; soft contact lenses may absorb and concentrate irritants. A written policy document,
describing the wearing of lens or restrictions on use, should be created for each workplace or task. This should include areview of lens absorption and adsorption for the class of chemicals in use and an account of injury experience. Medical andfirst-aid personnel should be trained in their removal and suitable equipment should be readily available. In the event ofchemical exposure, begin eye irrigation immediately and remove contact lens as soon as practicable. Lens should be removed atthe first signs of eye redness or irritation - lens should be removed in a clean environment only after workers have washedhands thoroughly. [CDC NIOSH Current Intelligence Bulletin 59]. HANDS/FEET ■ Suitability and durability of glove type is dependent on usage. Important factors in the selection of gloves include: such as: • frequency and duration of contact, • chemical resistance of glove material, • glove thickness and • dexterity. • Wear chemical protective gloves, eg. PVC. • Wear safety footwear or safety gumboots, eg. Rubber. OTHER • Overalls. • P.V.C. apron. • Barrier cream. • Skin cleansing cream. ENGINEERING CONTROLS ■ Local exhaust ventilation usually required. If risk of overexposure exists, wear approved respirator. Section 9 - PHYSICAL AND CHEMICAL PROPERTIES APPEARANCE White liquid with a characteristic odour; mixes with water. PHYSICAL PROPERTIES Liquid. Mixes with water. continued. Epirez Ezirender HB Primer Chemwatch Material Safety Data Sheet Issue Date: 21-Jan-2011 CHEMWATCH 5139-85 Version No:3 CD 2011/1 Page 5 of 6 Section 9 - PHYSICAL AND CHEMICAL PROPERTIES Section 10 - STABILITY AND REACTIVITY CONDITIONS CONTRIBUTING TO INSTABILITY • Presence of incompatible materials. • Product is considered stable. • Hazardous polymerisation will not occur. For incompatible materials - refer to Section 7 - Handling and Storage. Section 11 - TOXICOLOGICAL INFORMATION POTENTIAL HEALTH EFFECTS ACUTE HEALTH EFFECTS
■ HARMFUL- May cause lung damage if swallowed. TOXICITY AND IRRITATION ■ Not available. Refer to individual constituents. Section 12 - ECOLOGICAL INFORMATION Ecotoxicity Ingredient Section 13 - DISPOSAL CONSIDERATIONS
• Recycle wherever possible. • Consult manufacturer for recycling options or consult local or regional waste management authority for disposal if no suitable treatment or disposal facility can be identified. • Dispose of by: burial in a land-fill specifically licenced to accept chemical and / or pharmaceutical wastes or incineration in a licenced apparatus (after admixture with suitable combustible material). • Decontaminate empty containers. Observe all label safeguards until containers are cleaned and destroyed. Section 14 - TRANSPORTATION INFORMATION HAZCHEM: None continued. Epirez Ezirender HB Primer Chemwatch Material Safety Data Sheet Issue Date: 21-Jan-2011 CHEMWATCH 5139-85 Version No:3 CD 2011/1 Page 6 of 6 Section 14 - TRANSPORTATION INFORMATION
NOT REGULATED FOR TRANSPORT OF DANGEROUS GOODS: UN, IATA, IMDG
Section 15 - REGULATORY INFORMATION REGULATIONS Regulations for ingredients ammonium hydroxide (CAS: 1336-21-6) is found on the following regulatory lists; "Australia Hazardous Substances","Australia Inventory of Chemical Substances (AICS)","CODEX General Standard for Food Additives (GSFA) - Additives Permitted for Use in Food in General, Unless Otherwise Specified, in Accordance with GMP","IMO MARPOL 73/78 (Annex II) - List of Noxious Liquid Substances Carried in Bulk","International Council of Chemical Associations (ICCA) - High Production Volume List","International Fragrance Association (IFRA) Survey: Transparency List","OECD Representative List of High Production Volume (HPV) Chemicals" ethylene glycol (CAS: 107-21-1) is found on the following regulatory lists; "Australia Exposure Standards","Australia Hazardous Substances","Australia High Volume Industrial Chemical List (HVICL)", "Australia Inventory of Chemical Substances (AICS)","Australia National Pollutant Inventory","IMO IBC Code Chapter 17: Summary of minimum requirements","IMO MARPOL 73/78 (Annex II) - List of Noxious Liquid Substances Carried in Bulk","IMO Provisional Categorization of Liquid Substances - List 2: Pollutant only mixtures containing at least 99% by weight of components already assessed by IMO","International Council of Chemical Associations (ICCA) - High Production Volume List","International Fragrance Association (IFRA) Survey: Transparency List","OECD Representative List of High Production Volume (HPV) Chemicals" No data for Epirez Ezirender HB Primer (CW: 5139-85) Section 16 - OTHER INFORMATION
■ Classification of the preparation and its individual components has drawn on official and authoritative sources as well as independent review by the Chemwatch Classification committee using available literature references. A list of reference resources used to assist the committee may be found at: www.chemwatch.net/references.
■ The (M)SDS is a Hazard Communication tool and should be used to assist in the Risk Assessment. Many factors determine whether the reported Hazards are Risks in the workplace or other settings. This document is copyright. Apart from any fair dealing for the purposes of private study, research, review orcriticism, as permitted under the Copyright Act, no part may be reproduced by any process without writtenpermission from CHEMWATCH. TEL (+61 3) 9572 4700.
Issue Date: 21-Jan-2011Print Date: 5-Apr-2011
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Epirez Ezirender HB Primer