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2 Sterling Avenue Manurewa, Auckland Tel: 09 270 4157 Fax: 09 270 4159 www.nufarm.co.nz EMERGENCY INFORMATION AND STORAGE GUIDE / DANGEROUS GOODS DECLARATION
3 566 Insecticide
Substance: Bright yellow liquid, (emulsifiable concentrate) containing 475g/L pirimiphos-methyl (CAS No. 29232-93-7 )and 25g/L permethrin
(CAS No. 52645-53-1)
Proper shipping name: FLAMMABLE LIQUID, N.O.S. (hydrocarbon)
DG Class:
Subsidiary
Flash Point
HAZCHEM:
Marine Pollutant:
Maximum Transport
Risk Class:
Quantity:
Hazard Classifications:
Tracking Required
Approved Handler:
IER Guide:
3.1C, 6.1D, 6.3B, 6.4A, 6.5A, 6.5B, 6.8B, 6.9A, 9.1A, 9.3A, 9.4A EMERGENCY PROCEDURES
24 HOUR ADVICE IN AN EMERGENCY ONLY: 0800 651 911
IF THIS HAPPENS
Tanker/Vehicle
Switch off engine and electrical equipment. Keep people away, warn other traffic. Check for spills, leaks. Accident
Call the emergency services: Dial 111
Spill or leak
Eliminate all ignition sources and naked lights. Use non-sparking utensils. Wear PVC overalls, chemical resistant gloves, respirator and safety goggles. Prevent further spillage. Absorb spilled product and place in sealable container for disposal. Wash down affected area with water plus detergent. Absorb and collect washings and place in the same sealable container for disposal. Seek advice from the local authority regarding disposal. Call the Fire Service: Dial 111. Wear PVC protective clothing and breathing apparatus. Extinguish fires with foam, dry
chemical or carbon dioxide. During a fire toxic fumes may be released. Cool sealed drums with water to prevent rupture
due to thermal expansion. Contain run-off. Keep non-involved persons away.
FIRST AID
If Swallowed:
Do NOT induce vomiting. For advice contact the National Poisons Centre 0800 POISON (0800 764 766) or a doctor
immediately
.
If in Eyes:
Hold eyelids apart and flush the eye continuously with running water for at least 15 minutes. Get medical attention. If on Skin:
If skin or hair contact occurs, remove contaminated clothing and flush skin and hair with running water. Do not scrub the skin. If Inhaled:
Remove patient to fresh air. If not breathing, give artificial respiration, preferably mouth-to-nose. Get medical attention if symptoms develop. STORAGE AND SEGREGATION SUMMARY
Storage: Store in original container in a cool, dry, ventilated place away from direct heat or direct sunlight. Store away from foodstuffs,
children and animals. Keep container sealed when not in use.
Aggregate Storage Volume Thresholds: When stored with substances of the same hazard the aggregate quantity must be considered. For full details refer to
the current NZS8409 Management of Agrichemicals and the HSNO Regulations.
Location Certificate:
Hazardous
Number of Fire
Emergency
Emergency
Secondary
Atmosphere Zone:
Extinguishers:
Information:
Containment:
Note: Farms > 4 ha are exempt but with controls. DO NOT Store or Load With:
Segregate From:
Class 1, 2.1, 2.3, 4.2, 5.1, 5.2, 7 substances, food items Class 4.3 (by at least 3 metres horizontally on a vehicle) Class 4.2, 4.3, 5.1, 5.2, food items (in a segregation device) Segregation: Check the latest Land Transport Rule Dangerous Goods, Rule 45001 for additional information. Sea transport may require
additional segregation. Refer NZS5433 sea segregation for details.
No & Kind of Packages:
Gross Wgt:
Consignor:
Consignee:
Dangerous Goods Declaration:
I hereby declare that the contents of this consignment are fully and accurately described above by the proper shipping name and are classified, packaged, marked and labelled, and are in all respects in proper condition for transport according to the applicable international and national rules, regulations and legislation. Signature:
DISCLAIMER: The information provided above is based upon sources believed to be accurate. However, Nufarm Limited assumes no responsibility for the accuracy, completeness or suitability
of this information. The consignor and consignee are responsible to determine the suitability of this information for their particular purposes.

Source: http://www.farmlands.co.nz/userfiles/file/Other/Farmlands%20Hort%20Archives/Haznotes/Insecticides/attack.pdf

Doi:10.1016/s0140-6736(99)02423-x

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Canadian guidelines on sexually transmitted infections (2008 update)

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