Dipro_200000909_(en)_dif

Safety data sheet
according to 1907/2006/EC, Article 31
SECTION 1: Identification of the substance/mixture and of the company/undertaking
· 1.1 Product identifier
· Trade name: DINITROL 6064 BP-Härter für Spachtel
· 1.2 Relevant identified uses of the substance or mixture and uses advised against
No further relevant information available. · Application of the substance / the preparation Hardening agent/ Curing agent
· 1.3 Details of the supplier of the safety data sheet
· Manufacturer/Supplier:
DINOL GmbHPyrmonter Str. 76D-32676 LügdeTel: +49 5281 9829 80Fax: +49 5281 9829 860E-mail: msds@dinol.com · Further information obtainable from: Research & Development
· 1.4 Emergency telephone number: Giftnotruf Berlin +49(0)30 30686 790 Beratung in Deutsch und Englisch.
SECTION 2: Hazards identification
· 2.1 Classification of the substance or mixture
· Classification according to Directive 67/548/EEC or Directive 1999/45/EC
R43: May cause sensitisation by skin contact. R50: Very toxic to aquatic organisms. · Information concerning particular hazards for human and environment:
The product has to be labelled due to the calculation procedure of the "General Classification guideline forpreparations of the EU" in the latest valid version. · Classification system:
The classification is according to the latest editions of the EU-lists, and extended by company and literature data. · 2.2 Label elements
· Labelling according to EU guidelines:
The product has been marked in accordance with EU Directives / respective national laws.
The product has been classified and marked in accordance with EU Directives / Ordinance on HazardousMaterials.
The R and S phrases may be omitted if packaging contains no more than 0.125 litre. · Code letter and hazard designation of product:
Xi IrritantO OxidisingN Dangerous for the environment Safety data sheet
according to 1907/2006/EC, Article 31
Trade name: DINITROL 6064 BP-Härter für Spachtel
· Hazard-determining components of labelling:
· Risk phrases:
7 May cause fire.
36 Irritating to eyes.
43 May cause sensitisation by skin contact.
50 Very toxic to aquatic organisms. · Safety phrases:
Keep out of the reach of children. Keep container tightly closed in a cool place. Keep away from reducing agents, heavy metal compounds, acids and alkalis. 36/37/39 Wear suitable protective clothing, gloves and eye/face protection.
46 If swallowed, seek medical advice immediately and show this container or label. Dispose of this material and its container to hazardous or special waste collection point. · 2.3 Other hazards
· Results of PBT and vPvB assessment
· PBT: Not applicable.
· vPvB: Not applicable.
SECTION 3: Composition/information on ingredients
· 3.2 Chemical characterization: Mixtures
· Description: Mixture of substances listed below with additions.
· Dangerous components:
Eye Irrit. 2, H319; Skin Sens. 1, H317 Acute Tox. 4, H302; Skin Irrit. 2, H315; Eye Irrit. 2, H319 · Additional information: For the wording of the listed risk phrases refer to section 16.
SECTION 4: First aid measures
· 4.1 Description of first aid measures
· General information: Personal protection for the First Aider.
· After inhalation:
Take affected persons into fresh air and keep quiet.
Supply fresh air and to be sure call for a doctor.
In case of unconsciousness place patient stably in side position for transportation. · After skin contact:
Immediately wash with water and soap and rinse thoroughly.
If skin irritation continues, consult a doctor. · After eye contact:
Rinse opened eye for several minutes under running water. If symptoms persist, consult a doctor. · After swallowing: If symptoms persist consult doctor.
· 4.2 Most important symptoms and effects, both acute and delayed No further relevant information available.
Safety data sheet
according to 1907/2006/EC, Article 31
Trade name: DINITROL 6064 BP-Härter für Spachtel
· 4.3 Indication of any immediate medical attention and special treatment needed
No further relevant information available. SECTION 5: Firefighting measures
· 5.1 Extinguishing media
· Suitable extinguishing agents:
CO2, powder or water spray. Fight larger fires with water spray or alcohol resistant foam. · 5.2 Special hazards arising from the substance or mixture
Carbon monoxide (CO)Under certain fire conditions, traces of other toxic gases cannot be excluded. · 5.3 Advice for firefighters
· Protective equipment: Do not inhale explosion gases or combustion gases.
· Additional information
Cool endangered receptacles with water spray.
Collect contaminated fire fighting water separately. It must not enter the sewage system. SECTION 6: Accidental release measures
· 6.1 Personal precautions, protective equipment and emergency procedures Keep away from ignition sources.
· 6.2 Environmental precautions:
Do not allow product to reach sewage system or any water course.
Inform respective authorities in case of seepage into water course or sewage system.
Do not allow to enter sewers/ surface or ground water. · 6.3 Methods and material for containment and cleaning up:
Dispose contaminated material as waste according to item 13. · 6.4 Reference to other sections
See Section 7 for information on safe handling.
See Section 8 for information on personal protection equipment.
See Section 13 for disposal information. SECTION 7: Handling and storage
· 7.1 Precautions for safe handling
Keep receptacles tightly sealed.
Store in cool, dry place in tightly closed receptacles.
Keep away from heat and direct sunlight.
Do not refill residue into storage receptacles.
Restrict the quantity stored at the work place.
Handle with care. Avoid jolting, friction and impact. · 7.2 Conditions for safe storage, including any incompatibilities
· Storage:
· Requirements to be met by storerooms and receptacles:
Store only in the original receptacle.
Prevent any seepage into the ground.
Use only receptacles specifically permitted for this substance/product. · Information about storage in one common storage facility:
Do not store together with reducing agents, heavy-metal compounds, acids and alkalis. · Further information about storage conditions: Keep container tightly sealed.
Safety data sheet
according to 1907/2006/EC, Article 31
Trade name: DINITROL 6064 BP-Härter für Spachtel
· 7.3 Specific end use(s) No further relevant information available.
SECTION 8: Exposure controls/personal protection
· Additional information about design of technical facilities: No further data; see item 7.
· 8.1 Control parameters
· Ingredients with limit values that require monitoring at the workplace:
94-36-0 benzoyl peroxide
· Additional information: The lists valid during the making were used as basis.
· 8.2 Exposure controls
· Personal protective equipment:
· General protective and hygienic measures:
Keep away from foodstuffs, beverages and feed.
Immediately remove all soiled and contaminated clothingWash hands before breaks and at the end of work.
Avoid contact with the eyes.
Avoid contact with the eyes and skin. · Respiratory protection: Not required.
· Protection of hands:
· Material of gloves
Butyl rubberChloroprene rubberThe selection of the suitable gloves does not only depend on the material, but also on further marks of quality andvaries from manufacturer to manufacturer. As the product is a preparation of several substances, the resistance ofthe glove material can not be calculated in advance and has therefore to be checked prior to the application. · Penetration time of glove material
The exact break trough time has to be found out by the manufacturer of the protective gloves and has to beobserved. · Not suitable are gloves made of the following materials:
Leather glovesStrong material gloves · Eye protection:
· Body protection: Protective work clothing
Safety data sheet
according to 1907/2006/EC, Article 31
Trade name: DINITROL 6064 BP-Härter für Spachtel
SECTION 9: Physical and chemical properties
· 9.1 Information on basic physical and chemical properties
· General Information
· Appearance:
Form:
Colour:
· Odour:
· Odour threshold:
· pH-value:
· Change in condition
Melting point/Melting range:
Boiling point/Boiling range:
· Flash point:
· Flammability (solid, gaseous):
· Ignition temperature:
Decomposition temperature:
· Self-igniting:
· Danger of explosion:
· Explosion limits:
Lower:
Upper:
· Vapour pressure At 20 °C:
· Density At 20 °C:
· Relative density
· Vapour density
· Evaporation rate
· Solubility in / Miscibility with
water:
· Partition coefficient (n-octanol/water): Not determined.
· Viscosity:
Dynamic At 20 °C:
Kinematic:
· Solvent content:
Organic solvents:
Solids content:
· 9.2 Other information
No further relevant information available. · VOC (EU):
· VOCV:
SECTION 10: Stability and reactivity
· 10.1 Reactivity
· 10.2 Chemical stability
· Thermal decomposition / conditions to be avoided: No decomposition if used according to specifications.
Safety data sheet
according to 1907/2006/EC, Article 31
Trade name: DINITROL 6064 BP-Härter für Spachtel
· 10.3 Possibility of hazardous reactions Reacts with reducing agents.
· 10.4 Conditions to avoid No further relevant information available.
· 10.5 Incompatible materials: No further relevant information available.
· 10.6 Hazardous decomposition products: Carbon monoxide
· Additional information:
As long as the prescribed application concentrations are maintained there is no danger that stable emulsions willform. SECTION 11: Toxicological information
· 11.1 Information on toxicological effects
· Acute toxicity:
· LD/LC50 values relevant for classification:
94-36-0 benzoyl peroxide
Inhalative LC50/4 h > 24.3 mg/l (RAT) · Primary irritant effect:
· on the skin: No irritant effect.
· on the eye: Irritating effect.
· Sensitization: Sensitization possible through skin contact.
· Additional toxicological information:
The product shows the following dangers according to the calculation method of the General EU ClassificationGuidelines for Preparations as issued in the latest version:Irritant SECTION 12: Ecological information
· 12.1 Toxicity
· Aquatic toxicity:
94-36-0 benzoyl peroxide
EC50/48 h 0.11 mg/l (DAPHNIA MAGNA) · 12.2 Persistence and degradability No further relevant information available.
· 12.3 Bioaccumulative potential No further relevant information available.
· 12.4 Mobility in soil No further relevant information available.
· Ecotoxical effects:
· Remark: Very toxic for fish
· Additional ecological information:
· General notes:
Water hazard class 2 (German Regulation) (Self-assessment): hazardous for waterDo not allow product to reach ground water, water course or sewage system.
Danger to drinking water if even small quantities leak into the ground.
Also poisonous for fish and plankton in water bodies.
Very toxic for aquatic organisms · 12.5 Results of PBT and vPvB assessment
· PBT: Not applicable.
· vPvB: Not applicable.
· 12.6 Other adverse effects No further relevant information available.
Safety data sheet
according to 1907/2006/EC, Article 31
Trade name: DINITROL 6064 BP-Härter für Spachtel
SECTION 13: Disposal considerations
· 13.1 Waste treatment methods
· Recommendation
Must not be disposed together with household garbage. Do not allow product to reach sewage system. · European waste catalogue
16 00 00 WASTES NOT OTHERWISE SPECIFIED IN THE LIST 16 09 03* peroxides, for example hydrogen peroxide 16 00 00 WASTES NOT OTHERWISE SPECIFIED IN THE LIST 16 09 04* oxidising substances, not otherwise specified 15 00 00 WASTE PACKAGING; ABSORBENTS, WIPING CLOTHS, FILTER MATERIALS AND PROTECTIVE CLOTHING NOT OTHERWISE SPECIFIED 15 01 00 packaging (including separately collected municipal packaging waste) 15 01 10* packaging containing residues of or contaminated by dangerous substances · Uncleaned packaging:
· Recommendation: Disposal must be made according to official regulations.
SECTION 14: Transport information
· 14.1 UN-Number
· ADR, IMDG, IATA
· 14.2 UN proper shipping name
· ADR
3108 ORGANIC PEROXIDE TYPE E, SOLID · IMDG
ORGANIC PEROXIDE TYPE E, SOLID (DIBENZOYLPEROXIDE), MARINE POLLUTANT · IATA
· 14.3 Transport hazard class(es)
· ADR, IMDG
· Class
· Label
· IATA
· Class
· Label
· 14.4 Packing group
· ADR, IMDG, IATA
Safety data sheet
according to 1907/2006/EC, Article 31
Trade name: DINITROL 6064 BP-Härter für Spachtel
· 14.5 Environmental hazards:
· Marine pollutant:
· Special marking (ADR):
· 14.6 Special precautions for user
· 14.7 Transport in bulk according to Annex II of
MARPOL73/78 and the IBC Code
· Transport/Additional information:
· ADR
· Limited quantities (LQ)
· Transport category
· Tunnel restriction code
SECTION 15: Regulatory information
· 15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
· Labelling according to EU guidelines:
The product has been marked in accordance with EU Directives / respective national laws.
The product has been classified and marked in accordance with EU Directives / Ordinance on HazardousMaterials.
The R and S phrases may be omitted if packaging contains no more than 0.125 litre. · Code letter and hazard designation of product:
Xi IrritantO OxidisingN Dangerous for the environment · Hazard-determining components of labelling:
· Risk phrases:
7 May cause fire.
36 Irritating to eyes.
43 May cause sensitisation by skin contact.
50 Very toxic to aquatic organisms. · Safety phrases:
Keep out of the reach of children. Keep container tightly closed in a cool place. Keep away from reducing agents, heavy metal compounds, acids and alkalis. 36/37/39 Wear suitable protective clothing, gloves and eye/face protection.
46 If swallowed, seek medical advice immediately and show this container or label. Dispose of this material and its container to hazardous or special waste collection point. · National regulations:
· Waterhazard class: Water hazard class 2 (Self-assessment): hazardous for water.
· Other regulations, limitations and prohibitive regulations
UVV Umgang mit Gefahrstoffen( BGV B1)UVV Organische Peroxide (BGV B4) Safety data sheet
according to 1907/2006/EC, Article 31
Trade name: DINITROL 6064 BP-Härter für Spachtel
· 15.2 Chemical safety assessment: A Chemical Safety Assessment has not been carried out.
SECTION 16: Other information
This information is based on our present knowledge. However, this shall not constitute a guarantee for anyspecific product features and shall not establish a legally valid contractual relationship. · Relevant phrases
Heating may cause a fire or explosion. May cause an allergic skin reaction. Extreme risk of explosion by shock, friction, fire or other sources of ignition. R36/38 Irritating to eyes and skin.
R43 May cause sensitisation by skin contact. · Department issuing MSDS: Research & Development
· Contact: Kontakt: msds@dinol.com oder Tel.: 0049 (0)5281 982 980
· * Data compared to the previous version altered.

Source: http://www.dinitrol.co.uk/Portals/0/docs/msds/DINITROL%206064%20MSDS.pdf