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12271 - LUBRIMATIC MULTI-PURPOSE LITHIUM GREASE MATERIAL SAFETY DATA SHEET
LUBRIMATIC MULTI-PURPOSE LITHIUM GREASE
(11300-11302-11306-11315-11316-11328-11330-11332)
1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION
TRADE NAME
PRODUCT USE
SUPPLIER
Chemtool IncorporatedP.O. Box 5388200 Ridgefield RoadCrystal Lake, IL 60039-0538 USATel: (815) 459-1250Fax: (815) 459-1955 EMERGENCY TELEPHONE
InfotracU.S. and Canada - (800) 535-5053Outside the U.S. and Canada - +01-352-323-3500 2. COMPOSITION, INFORMATION ON INGREDIENTS
INGREDIENT NAME
LUBRICANT BASE OIL (PETROLEUM), HIGHLY REFINED**(2) *PHOSPHORODITHIOIC ACID, O,O-DI-C1-14-ALKYL ESTERS, ZINC SALTS *BENZENESULFONIC ACID, DODECYL-, CALCIUM SALT *ANTIMONY DIALKYLDITHIOCARBAMATE (NJTSRN 800983-5015P OR CAS# 15890-25-2) * This chemical(s) is hazardous according to OSHA/WHIMIS criteria COMPOSITION COMMENTS
Refer to section eight for exposure limits on ingredients. Chemical ingredients not regulated by OSHA or SARA are treated confidentially. **(2) The base oil for this product can be a mixture of any of the following highlyrefined petroleum streams:CAS 64741-88-4; CAS 64741-89-5; CAS 64741-96-4; CAS 64741-97-5; CAS64742-01-4; CAS 64742-52-5; CAS 64742-53-6; CAS 64742-54-7; CAS 64742-55-8;CAS 64742-56-9; CAS 64742-57-0; CAS 64742-62-7; CAS 64742-63-8; CAS64742-65-0; CAS 72623-83-7; CAS 72623-85-9; CAS 72623-86-0; CAS 72623-87-1.
Carcinogenicity: The petroleum base oils contained in this product have been highly 12271 - LUBRIMATIC MULTI-PURPOSE LITHIUM GREASE (11300) refined by a variety of processes including solvent extraction, solvent dewaxing andhydrotreating to remove aromatics and improve performance characteristics. None ofthe oils used are listed as a carcinogen by NTP, IARC, or OSHA.
3. HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW
HEALTH HAZARDS, GENERAL
Exposure to vapors generated at high temperatures may cause respiratory irritation.
SENSITIZATION
CARCINOGENICITY
See Section 11 for carcinogenicity data of ingredients.
HEALTH WARNINGS
INHALATION. Heating can generate vapors that may cause respiratory irritation,nausea and headaches. Inhalation hazard at room temperature is unlikely due to thelow volatility of this product. SKIN CONTACT. Repeated or prolonged contact canresult in drying of the skin. EYE CONTACT. Irritating. INGESTION. Can cause stomachache and vomiting. Main hazard, if ingested, is aspiration into the lungs andsubsequent pneumonitis.
ROUTE OF ENTRY
Inhalation. Skin and/or eye contact. Ingestion.
MEDICAL SYMPTOMS
MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE: Not determined 4. FIRST AID MEASURES
INHALATION
Vapor inhalation under ambient conditions is normally not a problem. If overcome byvapor of hot product, immediately remove from source of exposure. Move the exposedperson to fresh air at once. For breathing difficulties oxygen may be necessary. Getmedical attention if any discomfort continues.
Rinse the eye with water immediately. Continue to rinse for at least 15 minutes.
Contact physician if discomfort continues.
Remove contaminated clothing. Wash skin thoroughly with soap and water. Getmedical attention if any discomfort continues.
INGESTION
DO NOT INDUCE VOMITING! Get medical attention immediately! 5. FIRE FIGHTING MEASURES
FLASH POINT (°C)
224 (435°F) Cd OC (Cleveland open cup).
FLAMMABILITY LIMIT - LOWER(%)
FLAMMABILITY LIMIT - UPPER(%)
EXTINGUISHING MEDIA
Use: Carbon dioxide (CO2). Dry chemicals, sand, dolomite etc. Alcohol resistantfoam. Water spray, fog or mist.
SPECIAL FIRE FIGHTING
Use water to keep fire exposed containers cool and disperse vapors. Water spray PROCEDURES
may be used to flush spills away from exposures and dilute spills to non-flammablemixtures. Avoid water in straight hose stream; will scatter and spread fire. Keep run-offwater out of sewers and water sources. Dike for water control.
12271 - LUBRIMATIC MULTI-PURPOSE LITHIUM GREASE (11300) UNUSUAL FIRE & EXPLOSION
Pressure will increase in over heated, closed containers.
HAZARDOUS COMBUSTION
PRODUCTS
PROTECTIVE MEASURES IN CASE OF
Self-contained breathing equipment and chemical resistant clothing recommended.
6. ACCIDENTAL RELEASE MEASURES
PERSONAL PRECAUTIONS
PRECAUTIONS TO PROTECT THE
Keep product out of sewers and watercourses by diking or impounding. Advise ENVIRONMENT
authorities if product has entered or may enter sewers, watercourses or extensiveland areas. Assure conformity with applicable government regulations.
SPILL CLEAN-UP PROCEDURES
Contain spill. Absorb small amounts. Collect and return large amounts to shippingcontainer. Rinse area with water.
7. HANDLING AND STORAGE
HANDLING PRECAUTIONS
Ventilate well, avoid breathing vapors. Use approved respirator if air contamination isabove accepted level. Do not reuse container. Keep lid closed when not in use. Do notstore or mix with strong oxidizers. Avoid spilling, skin and eye contact. Eye wash andemergency shower must be available at the work place.
STORAGE PRECAUTIONS
Store separate from strong acids and oxidizers. Keep away from heat, sparks andopen flame.
STORAGE CRITERIA
8. EXPOSURE CONTROLS, PERSONAL PROTECTION
COMPONENT
ANTIMONY DIALKYLDITHIOCARBAMATE (NJTSRN OSHA INGREDIENT COMMENTS
**ACGIH A4: Not Classifiable as a Human Carcinogen. **NIOSH Ca: Potential Occupational Carcinogen.
PROTECTIVE EQUIPMENT
12271 - LUBRIMATIC MULTI-PURPOSE LITHIUM GREASE (11300) ENGINEERING CONTROLS
Use engineering controls to reduce air contamination to permissible exposure level.
VENTILATION
No specific ventilation requirements noted, but forced ventilation may still be requiredif air contamination exceeds acceptable level.
RESPIRATORS
No specific recommendation made, but respiratory protection may still be requiredunder exceptional circumstances when excessive air contamination exists.
PROTECTIVE GLOVES
Chemical resistant gloves recommended to prevent prolonged or repeated contact.
EYE PROTECTION
Wear splash-proof eye goggles to prevent any possibility of eye contact.
PROTECTIVE CLOTHING
Wear appropriate clothing to prevent repeated or prolonged skin contact.
HYGIENIC WORK PRACTICES
Wash at the end of each work shift and before eating, smoking and using the toilet.
9. PHYSICAL AND CHEMICAL PROPERTIES
APPEARANCE/PHYSICAL STATE
SOLUBILITY DESCRIPTION
Temperature (°C)
VAPOR DENSITY (air=1)
VAPOR PRESSURE
Temperature (°C)
EVAPORATION RATE
Reference
pH-VALUE, CONC. SOLUTION
10. STABILITY AND REACTIVITY
STABILITY
CONDITIONS TO AVOID
Avoid contact with acids and oxidizing substances.
HAZARDOUS POLYMERIZATION
POLYMERIZATION DESCRIPTION
HAZARDOUS DECOMPOSITION
PRODUCTS
12271 - LUBRIMATIC MULTI-PURPOSE LITHIUM GREASE (11300) 11. TOXICOLOGICAL INFORMATION
TOXICOLOGICAL INFORMATION
No experimental toxicological data on the preparation as such is available.
COMPONENT
LUBRICANT BASE OIL (PETROLEUM), HIGHLY REFINED**(2)
TOXICOLOGICAL DATA
TOXIC DOSE - LD 50
TOXIC DOSE - LD 50 SKIN
TOXIC CONC. - LC 50
COMPONENT
CARBON BLACK
TOXICOLOGICAL DATA
Carcinogenicity. WHMIS (Canada) D2AAcute toxicity. TCLo 6 hours. Inhalation. Rat. 7 mg/m3 TOXIC DOSE - LD 50
TOXIC DOSE - LD 50 SKIN
CARCINOGENICITY
NTP: Not listed. MAK-3 designation: Substances which cause concern that theycould be carcinogenic for man. IARC-2B: The agent is possibly carcinogenic tohumans (limited evidence of carcinogenicity in humans).
12. ECOLOGICAL INFORMATION
ECOLOGICAL INFORMATION
There is no ecological data on the product itself.
13. DISPOSAL CONSIDERATIONS
DISPOSAL METHODS
Spilled material, unused contents and empty containers must be disposed of inaccordance with local, state and federal regulations.
14. TRANSPORT INFORMATION
DOT HAZARD CLASS
TDGR CLASS
SEA TRANSPORT NOTES
AIR TRANSPORT NOTES
15. REGULATORY INFORMATION
US FEDERAL REGULATIONS
12271 - LUBRIMATIC MULTI-PURPOSE LITHIUM GREASE (11300) COMPONENT
LUBRICANT BASE OIL (PETROLEUM), HIGHLY REFINED**(2) BENZENESULFONIC ACID, DODECYL-, CALCIUM SALT ANTIMONY DIALKYLDITHIOCARBAMATE (NJTSRN 800983-5015P OR CAS# PHOSPHORODITHIOIC ACID, O,O-DI-C1-14-ALKYL ESTERS, ZINC SALTS REGULATORY STATUS
*** Indicates that no RQ is assigned to this generic or broad class, although the classis a CERCLA hazardous substance. See 50 Federal Register 13456 (April 4, 1985).
Values in Section 313 column represent Category Codes for reporting under Section313.
CLEAN AIR ACT
SARA HAZARD CATEGORIES
US STATE REGULATIONS
COMPONENT
REFINED**(2)PHOSPHORODITHIOIC ACID, O,O-DI-C1-14-ALKYL ESTERS, ZINC SALTSBENZENESULFONIC ACID, DODECYL-, CALCIUM STATE REGULATORY STATUS
CALIFORNIA PROPOSITION 65: This product may contain the following chemical(s)considered by the State of California's Safe Drinking Water and Toxic Enforcement Actof 1986 as causing cancer or reproductive toxicity, and for which warnings are nowrequired: Carbon black (airborne, unbound particles of respirable size), cancer hazard, CAS#1333-86-4. PENNSYLVANIA RIGHT-TO-KNOW: This product contains the following chemicalsthat the state of Pennsylvania has identified as Special Hazardous Substances (SHS),Environmental Hazards (EH), or both (ESHS). The PA regulations require that theMSDS identify all SHS or EH chemicals by chemical name, common name, and CASNumber if they comprise 0.01% or more. Zinc compounds regulated under CERCLA and SARA 313, Environmental Hazard Antimony compounds regulated under CERCLA and SARA 313, EnvironmentalHazard Benzenesulfonic acid, dodecyl-, sodium salt, Environmental Hazard, CAS#25155-30-0 WORKPLACE HAZARDOUS MATERIALS INFORMATION SYSTEM - WHMIS
This product has been classified in accordance with the hazard criteria of theControlled Products Regulations and the MSDS contains all the information requiredby the Controlled Products Regulations.
12271 - LUBRIMATIC MULTI-PURPOSE LITHIUM GREASE (11300) CONTROLLED PRODUCT
CLASSIFICATION
GLOBAL INVENTORIES
COMPONENT
BENZENESULFONIC ACID, DODECYL-, CALCIUM DSL ANTIMONY DIALKYLDITHIOCARBAMATE (NJTSRN NPRI 800983-5015P OR CAS# 15890-25-2)LUBRICANT BASE OIL (PETROLEUM), HIGHLY REFINED**(2)LITHIUM SOAP AND MIXED BASE THICKENERS PHOSPHORODITHIOIC ACID, O,O-DI-C1-14-ALKYL NPRI CANADA CEPA: All components of this product comply with new substancenotification requirements under the Canadian Environmental Protection Act (CEPA).
16. OTHER INFORMATION
NFPA-HMIS HAZARD RATING
Irritation, minor residual injury (1) - HMIS/NFPA FLAMMABILITY
REACTIVITY
PERSONAL PROTECTION INDEX
REVISION COMMENTS
Section 2: Ingredients Section 8: Exposure Limits. Section 11: Toxicological Information Section 15: WHMIS PREPARED BY
Replacement MSDS of
PRINTING DATE:
DISCLAIMER
While the information and recommendations set forth herein are believed to beaccurate as of the date thereof, the company makes no warranty with respect theretoand disclaims all liability from reliance therein.
* Information revised since previous MSDS version

Source: http://www.conncollege.com/media/website-media/offices/ehs/envhealthdocs/Lithium_Grease.pdf

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Safety Data Sheet according to Regulation (EC) No. 1907/2006 (REACH) Printed Carbonyl chloride 2500 1. Identification of the substance/mixture and of the company/undertaking Product identifier Name of product Name of substance Manufacturer/distributor GHC Gerling, Holz & Co. Handels GmbHRuhrstraße 113, D-22761 HamburgPhone +49 (0) 40 853 123-0, Fax +49 (0) 40 853 123-66

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